Welcome to Qingdao Xiangtai Material&Energy Technology Co., Ltd.
Our country mainly adopts the long-flow
converter steelmaking process, the converter steel slag accounts for 88% of the
total steel slag, the treatment process mainly adopts the water quenching
method, the environmental friendliness of the treatment process is low, the
iron and heat recovery effect is poor, and the degree of resource utilization
is unsatisfactory, its quantity increases about 120 million tons per month, a
large amount of storage or landfill destroys the ecological environment, and
environmental protection problems are serious, which seriously restricts the
iron and steel industry from achieving comprehensive green manufacturing.
The current prominent problems in the
resource utilization of converter slag are:
① converter slag contains free calcium
oxide (f-CaO) and free magnesium oxide (f-MgO), as well as trace amounts of FeS
and MnS. It is easy to form basic compounds when it meets water. It has poor
post-stability and volume stability when it used for cement material.
②the steel slag contains 20-30% FeOx
(calculated as Fe2O3) with basically no gelling activity, and the C3S and C2S
crystals are fully developed, with few defects, and poor gelling activity,
which makes the utilization rate improving.
③the iron-occurring phase in the steel slag
can be separated by weak magnetic field, and the proportion of metal iron and
magnetite is small, after iron removal, the total iron content of the steel
slag is still as high as 5-30%, and the grindability index is poor.
④melting steel slag contains a large amount
of heat energy (~1.2GJ in per ton slag, equal to the calorific value of 41kg
standard coal). The current treatment process mostly uses a large amount of
water medium to quench it, producing hot water or steam, and the heat medium is
low in heat (generally <100℃), and it contains lots of particulate impurities and suspended matter, which is taste badly and easily causes fouling of heat exchangers and conveying pipes. In fact, the overall heat recovery rate is very unsatisfactory.
Through in-depth research on the
"slag, iron, heat" characteristics of steel slag, we have formed a
converter slag gas-water quenching and alkali reduction magnetization heat
recovery technology.
Technical features:
1 The carbon fixation and alkali reduction
reaction of steel slag uses the steel mill's own lime kiln tail gas and
industrial water to form an atomized water-gas mixture to quickly quench the
molten steel slag, carbonation, and alkali reduction.
2 After the steel slag is de-alkalied and
modified, it is contacted with a limited amount of room temperature air, and
the secondary cooling is completed at the same time, and the FeO is
incompletely oxidized and converted into magnetite, the subsequent magnetic separation
helps to reduce the total iron content of the steel slag and increase the
grindability.
3 The radiant convection waste heat boiler
converts the calorific value of steel slag into high-temperature and
high-pressure steam, and the heat recovery rate is significantly improved, the
hot carrier gas after heat exchange still enters the existing lime kiln tail
gas purification equipment of the steel plant, which is extremely
environmentally friendly.
4 The quality of steel slag is weakly
alkaline, low RO phase, high C3S/C2S content and rich in high content of
amorphous components, with good stability and gelling activity.